I have long been a fan of rim lighting and, given the opportunity, would prefer to use it over a single light source. Rim lighting, which is often referred to as back light or even hair lights, is simply light placed on your subject which gives the appearance of a light outline. This technique pulls the subject off the background and offers some depth and dimension to what you are shooting.
This article outlines how to setup your lights to achieve such an effect and also covers some simple post-processing to help improve the final product.
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